Ambident reactivity of the nitrite ion revisited.
نویسندگان
چکیده
منابع مشابه
Control of the ambident reactivity of the nitrite ion.
In previous studies, it was reported that a neighbouring equatorial ester group is essential for a good yield of nitrite-mediated triflate inversion, whereas with neighbouring benzyl ether groups or axial ester groups, mixtures are generally produced. In the present study, the origin of this difference was addressed. The ambident reactivity of the nitrite ion has been found to be the cause of t...
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عنوان ژورنال:
- Angewandte Chemie
دوره 44 29 شماره
صفحات -
تاریخ انتشار 2005